First of all, I use the Weber 22.5" One Touch Gold Grill for my barbecuing.
With that said, I fill the small side of the grill with charcoal. I fill half full, scatter some wood chips, then fill the rest of the way and scatter some more chips (wood chunks work, also). I remove six briquettes from the stack, place them in the chimney. When they are started I put them on top of the unlit charcoal pile distributed across the top. When it starts smoking, I begin.
Dale53